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化合物[{(NCHCHNCH_3)CH}_3] Li Cl的合成与晶体结构 预览

Synthesis and Crystal Structureof [{(NCHCHNCH_3)CH}_3] LiCl
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摘要 甲基咪唑与氯化锂反应成功地合成了[{(NCHCHNCH3)CH}3LiCl]。化合物通过了元素分析,核磁和x-ray衍射表征。晶体结构表明其晶体属单斜晶系,空间群为C c,化学式为C12H18N6ClLi,晶胞参数为a=13.556(4)A°,b=9.061(3)A°C=12.287(4)A°,α(deg)=90 deg,β(deg)=93.671(6)deg,γ(deg)=90 deg,V(A°3)=1506.2(8)A°3,Z=4,最终R1=0.058,wR2=0.149. The reaction of LiCl with CH(MeNCHCHNH)} in a ratio of 1:3 gives the compound [{CH(MeNCHCHNH)}]3LiCl,The compound I has been characterized by the 1HNMR,elementary analysis and X-ray diffraction.The result shows that the crystal belongs to triclinic system.And the Empirical formula is C12H18 N6ClLi,a=13.556(4)A.,b=9.061(3) A.C=12.287(4)A.,α(deg)=90 deg,β(deg)=93.671(6)deg,γ(deg)=90 deg,V(A.3)=1506.2(8)A.3,Z=4,R1=0.058,wR2=0.149.
作者 王志国 李红波 刘婷 刘思曼 邓毅 WANG Zhi-guo,LI Hong-bo,LIU Ting,LIU Si-man DENG Yi(School of Chemistry & Chemical Engineering,Mianyang Normal University,Mianyang,Sichuan 621000)
出处 《绵阳师范学院学报》 2011年第2期 38-43,共6页 Journal of Mianyang Normal University
基金 四川省应用基础基金资助项目(2009JY0075) 绵阳师范学院学生科研(hx2010-2011-15)
关键词 咪唑 氯化锂 合成 结构 imidazole lithium chloride synthesis structure
作者简介 作者简介::王志国(1970~),男,博士,主要研究方向:金属有机物的合成及催化性能。E—mail:wangzhigu0224865@163.com
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